Jurassic magmatism related Pb-Zn-W-Mo polymetallic mineralization in the central Nanling Range,South China: Geochronologic,geochemical, and isotopic evidence from the Huangshaping deposit     

《Ore Geology Reviews》2017

The Nanling Range in South China is characterized by extensive Mesozoic magmatism and coeval nonferrous and rare metal mineralization. Huangshaping is a world-class Pb-Zn-W-Mo polymetallic skarn deposit in the central Nanling Range. Magmatic rocks occurring in this ore district include quartz porphyry, granite porphyry, granophyre, dacite porphyry, and aplite, with only the first three granitoids genetically associated with polymetallic mineralization. Most of the orebodies are constrained within the contact zones as skarn and veins between these granitic stocks and the carbonate wall rocks.Since the age of the quartz porphyry is still controversial, and studies of the dacite porphyry and aplite are absent, we focus on these magmatic rocks first. LA-ICP-MS zircon U-Pb dating suggests that the crystallization ages of the quartz porphyry, dacite porphyry, and aplite are 154.3 ± 1.9 Ma, 158.1 ± 0.8 Ma, and 148.4 ± 3.4 Ma, respectively. Combined with previously published age data, we infer the evolutionary sequence of magmatic rocks should be dacite porphyry → quartz porphyry → granite porphyry (granophyre) → aplite. The quartz porphyry, dacite porphyry, and aplite yield high contents of high field strength elements (Zr + Nb + Ce + Y = 255–440 ppm), high ratios of 10,000 × Ga/Al (2.6–3.2), and prominent depletions in Ba, Sr, Eu, P, and Ti, indicating their crustal affinities to A-type granites. They have negative ε_Nd(t) values (−9.4 to −7.0) and high initial Pb isotopic ratios (²⁰⁶Pb/²⁰⁴Pb_i = 18.307–18.644, ²⁰⁷Pb/²⁰⁴Pb_i = 15.689–15.742, ²⁰⁸Pb/²⁰⁴Pb_i = 38.589–38.986), suggesting that they were probably derived by partial melting of ancient granulitic crustal materials.The sulfide minerals exhibit a wide range of δ³⁴S_V-CDT values from −22.6 to 24.2‰, with ²⁰⁶Pb/²⁰⁴Pb of 17.669–19.708, ²⁰⁷Pb/²⁰⁴Pb of 15.492–15.714, and ²⁰⁸Pb/²⁰⁴Pb of 37.880–39.789, indicating that sulfur, lead, and other associated metals were derived from a mixture of magmatic components and the Carboniferous wall rocks. Fluid inclusions in pyrrhotite, sphalerite, and marmatite samples have ³He/⁴He ratios of 0.12 to 1.53 Ra, with calculated mantle helium proportions of 1.3 to 18.9%, indicating a predominantly crustal origin for the ore fluids, with minor inputs from the mantle. The Huangshaping deposit is a typical example of the genetic relationship both spatially and temporally between Jurassic magmatism and polymetallic metallogeny in the Nanling Range.  相似文献   

Genesis of the Huangshannan high-Ni tenor magmatic sulfide deposit in the Eastern Tianshan,northwest China: Constraints from PGE geochemistry and Os–S isotopes     

《Ore Geology Reviews》2017

The Huangshannan magmatic Ni-Cu sulfide deposit is one of a group of Permian magmatic Ni-Cu deposits located in the southern Central Asian Orogenic belt in the Eastern Tianshan, northwest China. It is characterized by elevated Ni tenor (concentrations in recalculated 100% sulfide) in sulfide within ultramafic rocks (9–19 wt%), with values much higher than other deposits in the region. Sulfides of the Huangshannan deposit are composed of pentlandite, chalcopyrite, and pyrrhotite and the host rock is relatively fresh, indicating that the high-Ni tenor is a primary magmatic feature rather than formed by alteration processes. It is shown that sulfides with high-Ni tenor can be generated by sulfide-olivine equilibrium at an oxygen fugacity of QFM +0.5, for magmas containing 450 ppm Ni and 20% olivine. Ores with >10 wt% sulfur have relatively low PGE and Ni tenors compared to other ores, R factor (mass ratio of silicate to sulfide liquid) modeling of Ni indicates that they formed at moderate R values (150–600). Based on this constraint on R values, ores with <10 wt% sulfides in the Huangshannan deposit can be segregated from a similar parental magma with 0.05 ppb Os, 0.023 ppb Ir, and 0.5 ppb Pd at R values between 600 and 3000. This, coupled with the supra-cotectic proportions of sulfide liquid to cumulus silicates in the Huangshannan ores imply mechanical transport and deposition of sulfide liquid in a magma pathway or conduit, in which sulfides must have interacted with large volumes of silicate magma. Platinum and Pd depletion relative to other platinum group elements (PGEs) are observed in fresh and sulfide-rich samples (S > 4.5 wt%). As sulfide-rich samples are also depleted in Cu, and as interstitial sulfides in those samples are physically interconnected at a scale of several cms, the low Pt and Pd anomalies are attributed to solid Pt and Pd phases crystallization and retention with the monosulfide solid solution (MSS) and Cu-rich sulfide liquid percolation during MSS fractionation. This finding indicates that Pt anomalies in sulfide-rich rocks from magmatic Ni-Cu deposits in the Eastern Tianshan are the result of sulfide fractionation rather than a hydrothermal effect. ¹⁸⁷Os/¹⁸⁸Os_(278Ma) values of the lherzolite samples vary from 0.27 to 0.37 and γOs_(278Ma) values vary from 110 to 189, indicating significant magma interaction with crustal sulfides, rich in radiogenic Os. Well constrained γOs values and δ³⁴S values (−0.4 to 0.8‰) indicate that crustal contamination occurred at depth before the arrival of the magma in the Huangshannan chamber. Regionally, deposits with high-Ni tenor have not been reported other than the Huangshannan deposit; however, many intrusions with high-Ni contents in olivine are present in NW China, such as the Erhongwa, Poyi and Poshi intrusions. Those intrusions are capable of forming high-Ni tenor sulfides due to olivine-sulfide-silicate equilibrium and relative high-Ni content in parent magma, making them attractive exploration targets.  相似文献   

A comparison of Jiaojia- and Linglong-type gold deposit ore-forming fluids: Do they differ?     

《Ore Geology Reviews》2017

The Jiaodong peninsula contains the most important concentration of gold deposits in China, which can be divided into Jiaojia-type and Linglong-type deposits based on mineralization style. The former is characterized by disseminated- and stockwork-style mineralization hosted in first-order regional faults, with relatively larger tonnages and lower gold grades. The latter is characterized by massive auriferous quartz veins commonly hosted in subsidiary second- or third-order faults, with smaller tonnage but higher grade orebodies. Despite these differences, both groups of deposits have the same alteration assemblages, mineral paragenesis, element concentrations, and ore-forming ages.The mainly Jiaojia-type Luoshan gold deposit and the mainly Linglong-type Fushan gold deposit are characterized by H-O-S-Pb isotope data that indicate the ore-forming fluids have a dominantly metamorphic source. The fluids were derived during the Yanshanian orogenic event, and were most likely associated with dehydration and decarbonization processes near the top of the subducting paleo-Pacific plate. The Linglong-type ores have relatively lighter calculated δ¹⁸O compositions (−3.9 to −2.3‰) than the Jiaojia-type ores (0.3–8.0‰), possibly because of a greater degree of mixing with meteoric water. Petrographic, cathodoluminescence, microthermometric, and laser Raman spectroscopic analyses of fluid-inclusion assemblages in quartz from the two types of ores indicate fluids were similar, in both cases characterized by medium–high homogenization temperatures (211–393 °C), significant CO₂ (∼15% mol), minor CH₄ (⩽18% in the carbonic phase), and low salinity (⩽11.2 wt% NaCl eq.). The Linglong-type ores, however, have a wider range of CO₂ and CH₄ concentration and salinity than the Jiaojia-type ores. Fluid immiscibility, occurred in main ore stage of both ore types, with the trapping conditions of 77–185 MPa and 284–328 °C, although the unmixing is more intense and widespread in the Linglong-type ores. Both fluid-wallrock interaction and fluid immiscibility are important gold-deposition processes in the two types, but immiscibility is more important in the Linglong-type ores and that has led to the typical higher gold grade.In general, there is little geochemical differences between the ore-forming fluids for Jiaojia- and Linglong-type gold deposits. Both Jiaojia- and Linglong-type ores can exist in a single deposit and form in the same metallogenic event. The Linglong-type ores developed as more massive veins, because of their location in zones of more extensive extension and they lack significant post-ore cataclastic deformation.  相似文献   

Magmatic–hydrothermal processes in Sangdong W–Mo deposit,Korea: Study of fluid inclusions and 39Ar–40Ar geochronology     

《Ore Geology Reviews》2017

The Sangdong scheelite–molybdenite deposit in northeast South Korea consists of strata-bound orebodies in intercalated carbonate-rich layers in the Cambrian Myobong slate formation. Among them, the M1 layer hosts the main orebody below which lie layers of F1–F4 host footwall orebodies. Each layer was first skarnized with the formation of a wollastonite + garnet + pyroxene assemblage hosting minor disseminated scheelite. The central parts of the layers were subsequently crosscut by two series of quartz veining events hosting minor scheelite and major scheelite–molybdenite ores, respectively. The former veins associate amphibole–magnetite (amphibole) alteration, whereas the latter veins host quartz–biotite–muscovite (mica) alteration. Deep quartz veins with molybdenite mineralization are hosted in the Cambrian Jangsan quartzite formation beneath the Myobong formation. In the Sunbawi area, which is in close proximity to the Sangdong deposit, quartz veins with scheelite mineralization are hosted in Precambrian metamorphic basement. Three muscovite ³⁹Ar–⁴⁰Ar ages between 86.6 ± 0.2 and 87.2 ± 0.3 Ma were obtained from M1 and F2 orebodies from the Sangdong deposit and Sunbawi quartz veins. The Upper Cretaceous age of the orebodies is concordant with the published ages of the hidden Sangdong granite, 87.5 ± 4.5 Ma. This strongly suggests that the intrusion is causative for the Sangdong W–Mo ores and Sunbawi veins.Fluid inclusions in the quartz veins from the M1 and F2 orebodies, the deep quartz-molybdenite veins, and the Sunbawi veins are commonly liquid-rich aqueous inclusions having bubble sizes of 10–30 vol%, apparent salinities of 2–8 wt% NaCl eqv., and homogenization temperatures of 180–350 °C. The densities of the aqueous inclusions are 0.70–0.94 g/cm³. No indication of fluid phase separation was observed in the vein. To constrain the formation depth in the Sangdong deposit, fluid isochores are combined with Ti–in–quartz geothermometry, which suggests that the M1 and F2 orebodies were formed at depths of 1–3 km and 5–6 km below the paleosurface, respectively. The similarity of the Cs (cesium) concentrations and Rb/Sr ratios in the fluid inclusions of the respective orebodies indicate an origin from source magmas having similar degrees of fractionation and enrichment of incompatible elements such as W and Mo. High S concentrations in the fluids and possibly organic C in the sedimentary source likely promoted molybdenite precipitation in the Sangdong orebodies, whereas the scheelite deposition in the deep quartz–molybdenite veins hosted in the quartzite is limited by a lack of Ca and Fe in the hydrothermal fluids. The molybdenite deposition in the Sunbawi quartz–molybdenite veins hosted in the Precambrian metamorphic basement rocks was possibly limited by a lack of reducing agents such as organic C.  相似文献   

中国北方晚中生代陆相盆地红-黑岩系耦合产出对砂岩型铀矿成矿环境的制约   总被引：4，自引：3，他引：1       下载免费PDF全文

金若时  程银行  李建国  司马献章  苗培森  王少轶  奥琮  里宏亮  李艳锋  张天福 《中国地质》2017,44(2):205-223

为研究中国北方陆相盆地红层-黑色岩系对砂岩型铀成矿的制约,文章研究了国内外红-黑岩系与砂岩型铀矿赋存岩层的时空关系,筛选了10万余m岩心钻探资料,选择准噶尔、鄂尔多斯和松辽盆地这3个典型产铀盆地,通过编制盆地钻孔柱状图、典型地区连井剖面图及关键岩层的地球化学测试等方法,对红-黑岩系和砂岩型铀矿的赋存岩层进行了垂向、横向上综合分析与对比。研究发现:北方陆相盆地自西向东铀矿赋存地层的时代由中侏罗世过渡到晚白垩世;晚中生代至少存在6次大规模的富氧红层沉积事件:Ⅰ中侏罗世—晚侏罗世早期(BathonianOxfordian),Ⅱ早白垩世早中期(Berriasian-Barremian),Ⅲ早白垩世中期(Barremian),Ⅳ晚白垩世早期(Cenomanian),Ⅴ晚白垩世中期(Coniacian)和Ⅵ晚白垩世晚期(Campanian)。其中第Ⅰ、Ⅴ和Ⅵ期红层之下沉积了时代相近的黑色层,与之构成"红-黑岩系"的沉积结构,是北方砂岩型铀成矿的3个重要层位。典型盆地内地球化学表明,红层与黑色层的B、Sr和Cu元素含量及Fe~(2+)/Fe~(3+)、B/Ga、Sr/Cu和FeO/MnO比值具有明显的差异,结合黑色岩层中草莓状黄铁矿、碳屑、油斑和红层中碳酸盐岩的发育,认为红层为相对较强氧化环境,黑色层为相对较还原环境。连井剖面资料显示红层、黑色层与砂岩型铀矿空间关系密切,铀矿多产于红层与黑色层之间过渡带上,呈板状矿体赋存于灰色、绿灰色砂岩和细砂岩中。一般红层与黑色层垂向距离超过500 m不利于成矿。晚中生代陆相盆地内耦合产出的黑色岩系和红色岩系是古沉积环境由还原向氧化转变形成的垂向分带,前者为铀矿物质沉淀提供了"障",后者为表生流体溶解铀矿提供了"场"。文章初步提出了红-黑岩系垂向环境变化制约着北方陆相盆地砂岩型铀大规模成矿作用的新认识。这些认识不仅对砂岩型铀矿成矿环境、成矿规律及成矿模式研究具有重要意义,更对目前正在开展的砂岩型铀矿勘查工作具有实践指导意义。  相似文献   

会泽超大型富锗银铅锌矿床矿化-蚀变分带规律及构造的控制作用          下载免费PDF全文

李孜腾  韩润生  闫庆文 《中国地质》2017,44(2):316-330

会泽超大型富锗银铅锌矿床是川—滇—黔铅锌多金属成矿区滇东北矿集区的典型代表。基于大量的地表调研和坑道精细编录,通过赋矿白云岩的岩石学、地球化学与矿化蚀变分带规律、构造对矿化-蚀变带控制作用的研究,认为赋矿粗晶白云岩是成矿过程中白云石化的产物,具有典型的热液蚀变成因,与沉积-成岩成因的摆佐组细晶白云岩、白云质灰岩明显不同;根据矿石和蚀变围岩中铅锌矿物组成与矿化、蚀变程度及其分布特征,该矿床矿化-蚀变分带规律:从矿体到围岩依次为铅锌矿石—铅锌矿化黄铁矿带→铅锌矿化/黄铁矿化粗晶白云岩带→灰白色粗晶白云岩带、米黄色粗晶白云岩带、肉红色粗晶白云岩带、网脉状白云石化灰岩带(蚀变残留体)、弱白云石化灰岩带。矿化-蚀变带明显受冲断褶皱构造(矿山厂、麒麟厂、银厂坡斜冲断层及其派生褶皱)上盘的层间断裂带控制,形成了典型的"成矿构造-蚀变白云岩-铅锌矿体"的矿化结构。该认识不仅丰富了会泽型(HZT)铅锌矿床成矿理论,而且对指导滇东北铅锌矿集区,乃至川滇黔成矿区的资源危机矿山的综合地质研究与找矿勘查具有重要的现实意义。  相似文献   

庐枞盆地大倪庄铜矿床地质特征、成岩时代及成因探讨          下载免费PDF全文

王继强  孙维安  袁峰  尚世贵  周涛发  钟富明  张若飞 《中国地质》2017,44(1):86-100

大倪庄铜矿是庐枞盆地内部近年来发现的一处小型斑岩型矿床。本次工作以大倪庄铜矿为研究对象,基于详细的野外观察和系统的岩相学、矿相学工作,总结了矿床的蚀变特征,即主要发育:钾硅酸盐化、黄铁绢英岩化、青磐岩化、碳酸盐化蚀变;确定了矿化特征、矿物生成顺序并划分了成矿阶段,即:钾硅酸盐化阶段、硫化物阶段、碳酸盐化阶段,其中硫化物阶段可进一步划分为石英硫化物亚阶段、绿帘石-绿泥石亚阶段。通过对与成矿有关的侵入岩体(正长斑岩)采用LA-ICP-MS锆石U-Pb定年,获得正长斑岩LA-ICP-MS锆石U-Pb年龄为(126.6±1.8)Ma,形成时代为早白垩世,对应于盆地内双庙旋回岩浆侵入活动。通过与其他区域相似矿床对比分析,探究了此类矿床控矿因素,为该地区斑岩型铜矿找矿勘查提供参考。  相似文献   

地震作用下堆积体边坡的坡面变形与失稳机制     

孙志亮  孔令伟  郭爱国  田海 《岩土力学》2015,36(12):3465-3472

地震作用下堆积体边坡的动力响应特性十分复杂,单一抗震安全系数不足以评价其动力稳定性。通过大型振动台试验,研究了连续多级地震荷载作用下,地震波的类型、卓越频率及峰值加速度对堆积体边坡坡面永久位移的影响,并初步分析其失稳机制。试验结果表明,相同峰值加速度下振动型地震波比冲击型地震波更容易产生坡面永久位移,地震波卓越频率对坡面永久位移也有重要影响;堆积体边坡在峰值加速度apeak=0.2g时开始有大颗粒石砾滚落,对应的坡面永久位移在apeak=0.2g～0.3g之间开始产生并显著增大,另外利用考虑坡面几何形态变化的改进Newmark法对坡顶的永久位移进行了估算。通过坡面永久位移评价堆积体边坡的动力稳定性有一定合理性。  相似文献   

大功率激电测深法寻找焦家式深部金矿床的应用研究          下载免费PDF全文

王洪军  牛如宝  王秋兰 《山东国土资源》2012,28(10):25-28,31

大功率的激电测深法在寻找焦家式深部金矿中取得了大量的资料,由多次去除极化单元场的原理对导出大功率激电测深资料进行消除浅部强激电干扰异常,从而突出了深部矿床的激电异常,并利用处理后的激电测深曲线,定量求取了深部金矿蚀变矿化带的顶界面埋深。认为当供电极距达到一定值时,极化电场仍然会反映到地表,因此该方法可以寻找焦家式破碎带蚀变岩型的深部金矿床。  相似文献   

胶东玲珑矿田石英脉型金矿床中流体包裹体特征研究   总被引：2，自引：0，他引：2  

李洪奎  于学峰  沈昆  程伟  于雷亨 《山东国土资源》2012,28(11):1-8

玲珑矿田含有两种类型金矿床,一是蚀变岩型金矿床,二是石英脉型金矿床。该文重点研究玲珑金矿田西山矿区石英脉型金矿床中流体包裹体的特征。石英脉型金矿床分布在玲珑帚状构造之中,含金石英脉受"帚状构造"的断裂和节理控制,有300余条。流体包裹体显微观察研究表明,玲珑石英脉型金矿新鲜花岗岩和钾化花岗岩主要含有H2O包裹体,其次有少量H2O-CO2包裹体;(黄铁)绢英岩通常含较粗粒石英集合体,石英中有丰富的H2O,特别是H2O-CO2包裹体;金矿体(含金石英脉)含有明显数量的H2O-CO2包裹体;特别是存在较大的三相H2O-CO2包裹体。不同期次(世代)石英中H2O和H2O-CO2包裹体的大小、形态、相对含量和丰度变化较大。  相似文献